Polycarbonate Compatibility - Part II

 ANSI/EIA-564-1992 Validates Polycarbonate Compatibility

 

                                                         Figure 2 - Left                                    Figure 2 - Right

 

 

Test Procedure


Five EIA-564 specified stress levels can be required while the specimens are undergoing oven conditioning upwards to four temperatures levels. The polycarbonate specimens are first annealed and placed into strain jigs (Figure 2-left). The agent or material under consideration is applied or fabricated to make intimate contact with the polycarbonate specimens. The samples are placed into the oven at a recommended maximum temperature of 1850F.  Sometimes, specimens are conditioned at room temperature of 730F and evaluated before placement into the oven for exposure to heat. After five days, the sets are removed from the oven(s) and all specimens are visually inspected for crazing and cracking in comparison to an unstressed sample using microscopic mapping. Figure 2-Right illustrates uncut polycarbonate being microscopically photographed to serve as a benchmark against stressed specimens.

 

5. Test Specimens (Ref: EIA-564)

5.1 Test specimens are transparent injection molded polycarbonate IZOD bars per ASTM D256. Clean handling techniques should be observed in the preparation and utilization of the polycarbonate specimens.

6.4 Temperature (Ref: EIA 564)

Maintain one set of exposed and strained polycarbonate bars at each temperature being evaluated, namely 730F, 1200F, 158°F and 185°F +/-2°F for five days. Reapply agents that volatilize in order to maintain continued chemical exposure.

After five days, remove the bars from the jigs, wipe clean and inspect visually for crazes and cracks. Some organizations require testing at the maximum 185°F temperature only for 5 days using the strain jigs 1000, 1700, 2000, 2500 and 3400 psi. This serves as a “worst case” scenario at the 1850F temperature level.

The test, polycarbonate bars, which have been bent at various stress levels and exposed to the  supplier’s antistatic type agent or static packaging materials are then subjected to various temperatures for 5 days. Later, said specimens are examined for cracks or imperfections.

                 Table 11                      Highest Compatible Stress Level

5 Day

Température

730F

1200F

1580F

1850F

Stress (psi)

AMINE (Worst)

2500

1700

<1000

<1000

Stress (psi)

AMIDE (2nd Worst)

3400

2500

1700

1000

Stress (psi)

Co-Extruded (Good)

3400

3400

2500

2000

Stress (psi)

Controlled (Air only)

3400

3400

2500

2000

 

(1EOS/ESD Symposium in 1989 by Dr. Marv Havens of Cryovac2 )

According to Dr. Marv Havens, “A general rule for polycarbonate compatibility is that there be no serious crazing up to the 2000 psi stress level at 1580F.”The data in Table 1 gives the polycarbonate compatibility date for the three versions of Type II film from Marv Haven, Ph.D.   

                Table 2                           EIA 564 Full Testing Series

5 Day

Température

730F

1200F

1580F

1850F

Stress (psi) 1

1000

1000

1000

1000

Stress (psi) 2

1700

1700

1700

1700

Stress (psi) 3

2500

2500

2500

2500

Stress (psi) 4

3400

3400

3400

3400

                 Table 3                         Worst Case Request Option (5 days)

5 Day

Température

1850F

1850F

1850F

1850F

Stress (psi)

1000

1700

2500

3400

Passing at 1850F is therefore unnecessary to test at low temperatures.
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